The gcc-win32 build pages have been split into three areas:
Native win32 build environment, using Cygwin:
http://www.libsdl.org/extras/win32/cygwin/README.txt
Native win32 build environment, using MinGW:
http://www.libsdl.org/extras/win32/mingw32/README.txt
Cross-compiled win32 build environment under Linux:
http://www.libsdl.org/extras/win32/cross/README.txt